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Antiplatelet, Anticoagulant, and Fibrinolytic Drugs

Chapter 123 | Part 4: Oncology and Hematology · Part 4 – Hematologic Disorders & Hemostasis · Chapter 123


Key Clinical Points

  1. Arterial thrombi are platelet-rich (white); venous thrombi are fibrin-rich (red).
  2. Aspirin irreversibly acetylates COX-1, inhibiting thromboxane A2 synthesis.
  3. Thienopyridines (clopidogrel, prasugel) irreversibly block P2Y12 receptors; ticagrelor is a reversible P2Y12 inhibitor.
  4. GP IIb/IIIa antagonists (abciximab, eptifibatide, tirofiban) block the final common pathway of fibrinogen and von Willebrand factor (VWF) binding.
  5. Heparin binds antithrombin via a pentasaccharide sequence to inhibit factor Xa and thrombin; LMWH has a higher anti-factor Xa to anti-thrombin ratio than unfractionated heparin.
  6. Prasugrel is contraindicated in patients >75 years or with prior stroke/TIA.
  7. Ticagrelor is associated with dyspnea in up to 15% of patients.
  8. Vorapaxar inhibits thrombin-mediated activation by targeting the PAR-1 receptor.
  9. Warfarin's efficacy and dosage are influenced by CYP2C9 and VKORC1 polymorphisms.
  10. Fibrinolytic agents (alteplase, tenecteplase, reteplase) differ in half-life and resistance to PAI-1 inhibition.

1. DEFINITION & OVERVIEW

Thromboembolic disorders are major causes of morbidity and mortality. Thrombosis occurs in arteries or veins, with distinct mechanisms:

Arterial thrombosis: Platelet-rich, triggered by vessel injury and high shear forces (e.g., MI, stroke). ◦ Appearance: White due to platelet dominance. • Venous thrombosis: Fibrin-rich, initiated by stasis and tissue factor exposure (e.g., DVT, PE). ◦ Appearance: Red due to trapped RBCs.

1.1 Distinction Between Arterial and Venous Thrombosis

Key differences in clot composition and pathogenesis:

Arterial thrombosis: ◦ Platelet adhesion to collagen/VWF under high shear. ◦ Thromboxane A2 release amplifies platelet aggregation. ◦ GP IIb/IIIa receptor activation mediates fibrinogen bridging. • Venous thrombosis: ◦ Initiated by stasis and tissue factor exposure. ◦ Fibrin dominates due to low shear conditions. ◦ Antithrombin-heparin complex inhibits factor Xa and thrombin.


2. EPIDEMIOLOGY

Venous thrombosis (VTE) risk factors include:

Genetic: Factor V Leiden, prothrombin G20210A mutation, antithrombin/protein C/S deficiencies. • Acquired: Obesity, pregnancy, cancer, immobility, hyperhomocysteinemia.

Incidence: 4.3-fold increased risk in pregnant/postpartum women (199.7 per 100,000 woman-years).


3. ETIOLOGY & PATHOPHYSIOLOGY

Thrombosis involves interplay between coagulation, fibrinolysis, and platelet activation:

Fibrinolytic defects: PAI-1 4G/5G polymorphism, TAFI elevation (linked to DVT/CVD). • Metabolic syndrome: Increased PAI-1, reduced fibrinolysis, procoagulant state. • Inflammation: Neutrophils/macrophages modulate thrombus formation/resolution.

3.1 Fibrinolysis and Thrombosis

• tPA/PAI-1 imbalance reduces fibrinolytic activity. • TAFI elevation stabilizes fibrin clots, increasing thrombotic risk.


4. CLINICAL FEATURES

Clinical manifestations depend on thrombus location:

Arterial: Acute MI (chest pain), ischemic stroke (neurological deficits), limb gangrene. • Venous: DVT (calf swelling, Homan's sign), PE (pleuritic chest pain, hypoxia).


5. DIFFERENTIAL DIAGNOSIS

Distinguish based on thrombus composition and clinical context:

Arterial vs venous: White vs red thrombi; acute vs chronic presentation. • Thrombophilia screening: Factor V Leiden, protein C/S levels, PAI-1 genotype.


6. DIAGNOSTIC APPROACH

  1. Initial Screening for DVT/PE:
  2. Perform D-dimer.
  3. Perform compression ultrasound.
  4. Perform CT pulmonary angiography.
  5. Genetic Testing (Indicated in recurrent VTE or family history):
  6. Factor V Leiden (PCR).
  7. Prothrombin G20210A mutation.
  8. Protein C/S activity assays.
  9. Fibrinolytic Assays:
  10. PAI-1 activity.
  11. TAFI plasma levels.

7. MANAGEMENT & TREATMENT

Therapeutic strategies depend on thrombus type:

Arterial: Antiplatelet agents (aspirin, clopidogrel) + anticoagulants (rivaroxaban). • Venous: LMWH/DOACs (apixaban, rivaroxaban) for DVT/PE. • Fibrinolytics: Systemic alteplase for massive PE; catheter-directed therapy for extensive DVT.

7.1 Antiplatelet Drugs

Mechanism of action and clinical application:

Aspirin: Irreversible COX-1 inhibition (75–325 mg/day). Inhibits TXA2 synthesis. • Thienopyridines: - Clopidogrel (75 mg/day): Requires CYP2C19 activation. - Prasugrel (10 mg/day): Requires CYP2C19 activation; contraindicated in patients >75 years or with prior stroke/TIA. • Ticagrelor: Reversible P2Y12 inhibitor (90 mg BID); associated with dyspnea in up to 15% of patients; discontinue 5 days before surgery. • Cangrelor: Reversible P2Y12 inhibitor. • GP IIb/IIIa Antagonists (Block final common pathway): - Abciximab (0.25 mg/kg IV). - Eptifibatide (180 mcg/kg IV). - Tirofiban.

7.2 Heparin and LMWH

Unfractionated Heparin: Binds antithrombin via pentasaccharide sequence; inhibits factor Xa and thrombin (requires chain length ≥18 units). • LMWH: Higher anti-factor Xa to anti-thrombin ratio than unfractionated heparin; more predictable response; lower risk of heparin-induced thrombocytopenia (HIT). • Fondaparinux: Synthetic pentasaccharide; specifically accelerates factor Xa inhibition by antithrombin; no thrombin activity.

7.3 Direct Thrombin Inhibitors

Used as alternatives or specific agents:

Desirudin (Half-life: 60 min IV). • Bivalirudin (Half-life: 25 min). • Argatroban (Half-life: 45 min).

7.4 DOACs

Direct Oral Anticoagulants:

Rivaroxaban: Factor Xa inhibitor; 80% bioavailability. • Apixaban: Factor Xa inhibitor; 60% bioavailability. • Edoxaban: Factor Xa inhibitor; 50% bioavailability. • Dabigatran: Thrombin inhibitor; 6% bioavailability.

7.5 Fibrinolytic Agents

Mechanism of action for clot dissolution:

Streptokinase: Binds to plasminogen → conformational change → activates additional plasminogen. • Alteplase (tPA): Standard tPA; contains F, EGF, K1, K2, and P domains. • Tenecteplase (TNK-tPA): Modified at P domain (substitution of "KHRR" with "AAAA" at positions 296–299); longer half-life; resistant to PAI-1 inhibition. • Reteplase (r-PA): Truncated variant; lacks F, EGF, and K1 domains.


8. PROGNOSIS & COMPLICATIONS

Major bleeding risks:

Aspirin: 1–3% annual risk; increased with combination therapy. • GP IIb/IIIa inhibitors: Thrombocytopenia (5% for abciximab, 1% for others). • Vorapaxar: Increased intracranial bleeding risk. • Heparin-Induced Thrombocytopenia (HIT): - Criteria: Platelet count ≤100,000/μL or a decrease in platelet count of ≥50%. - Management: 1. Stop all heparins. 2. Give alternative anticoagulant (argatroban, bivalirudin, fondaparinux, or rivaroxaban). 3. Do not give platelet transfusions. 4. Do not give warfarin until the platelet count returns to its baseline level; if warfarin was administered, give vitamin K to restore the INR to normal. 5. Evaluate for thrombosis, particularly deep vein thrombosis.


9. SPECIAL CONSIDERATIONS

Prasugrel: Contraindicated in patients >75 years or with prior stroke/TIA. • Ticagrelor: Discontinue 5 days before surgery; monitor for dyspnea (15%). • Warfarin: Dosage must be adjusted based on CYP2C9 and VKORC1 genotypes. • LMWH vs Heparin: LMWH preferred for predictable response and lower HIT risk.


10. KEY PEARLS & CLINICAL TRAPS

Aspirin Resistance: Not routinely tested; no proven benefit of higher doses. • Combination Therapy: Clopidogrel + aspirin reduces MI/stroke risk by 20% but increases bleeding (2%/year). • Ticagrelor: Dyspnea is common (15%) but typically self-limiting. • Fibrinolysis Regulation: PAI-1 and α_2-antiplasmin are the primary regulators of the fibrinolytic system.


Reference Tables

TABLE 123-1 Features of Gp IIb/IIIa Antagonists FEATURE Description

Harrison's 22e, p.945

FEATURE ABCIXIMAB EPTIFIBATIDE TIROFIBAN
Description Fab fragment of
humanized mouse
monoclonal antibody
Cyclical KGD-
containing
heptapeptide
Nonpeptidic RGD
mimetic
No Yes
Plasma half-life Short (min) Long (2.5 h) Long (2.0 h)
Long (days) Short (s)
Renal clearance No Yes Yes

TABLE 123-2 Pharmacokinetic and Biophysical Limitations of Heparin LIMITATIONS Poor bioavailability at low doses…

Harrison's 22e, p.947

LIMITATIONS MECHANISM
Poor bioavailability at low doses Binds to endothelial cells and
macrophages
Variable anticoagulant response Binds to plasma proteins whose levels
vary from patient to patient
Limited activity against factor Xa
incorporated in the prothrombinase
complex and thrombin bound to fibrin
Reduced capacity of heparin-
antithrombin complex to inhibit factor
Xa bound to activated platelets and
thrombin bound to fibrin

TABLE 123-3 Features of Heparin-Induced Thrombocytopenia FEATURES Thrombocytopenia Timing Type of heparin Type of…

Harrison's 22e, p.948

FEATURES DETAILS
Thrombocytopenia Platelet count of ≤100,000/μL or a decrease in platelet
count of ≥50%
Type of heparin More common with unfractionated heparin than low-
molecular-weight heparin
Thrombosis Venous thrombosis more common than arterial thrombosis

TABLE 123-5 Advantages of LMWH Over Heparin ADVANTAGE Better bioavailability and longer half- life after subcutaneous…

Harrison's 22e, p.948

ADVANTAGE CONSEQUENCE
Better bioavailability and longer half-
life after subcutaneous injection
Can be given subcutaneously once or
twice daily for both prophylaxis and
treatment

TABLE 123-4 Management of Heparin-Induced Thrombocytopenia Stop all heparins. Give an alternative anticoagulant, such…

Harrison's 22e, p.948

Stop all heparins.
Give an alternative anticoagulant, such as argatroban, bivalirudin, fondaparinux,
or rivaroxaban.
Do not give platelet transfusions.
Do not give warfarin until the platelet count returns to its baseline level. If
warfarin was administered, give vitamin K to restore the INR to normal.
Evaluate for thrombosis, particularly deep vein thrombosis.
Predictable anticoagulant response Coagulation monitoring is unnecessary
in most patients
Lower risk of osteoporosis Safer than heparin for extended
administration

TABLE 123-6 Comparison of LMWH and Fondaparinux FEATURES Number of saccharide units Catalysis of factor Xa inhibition…

Harrison's 22e, p.949

FEATURES LMWH FONDAPARINUX
Number of saccharide units 15–17 5
Yes
Catalysis of thrombin inhibition Yes No
90
Plasma half-life (h) 4 17
Yes
Induces release of tissue factor pathway inhibitor Yes No
Partially

TABLE 123-7 Comparison of the Properties of Desirudin, Bivalirudin, and Argatroban Molecular mass Site(s) of…

Harrison's 22e, p.950

DESIRUDIN BIVALIRUDIN ARGATROBAN
Molecular mass 7000 1980 527
Active site and
exosite 1
Active site and
exosite 1
Renal clearance Yes No No
No No
Plasma half-life (min) 60 (IV)
120–180 (SC)
25 45

TABLE 123-8 Frequencies of CYP2C9 Genotypes and VKORC1 Haplotypes in Different Populations and their Effect on Warfarin…

Harrison's 22e, p.951

GENOTYPE/
HAPLOTYPE
FREQUENCY, % PERCENTAGE
DOSE REDUCTION
COMPARED WITH
WILD-TYPE
CAUCASIANS AFRICAN
AMERICANS
(A/A)
ASIANS (A)
CYP2C9
1/1 70 90 95
1/2 17 2 0 22
1/3 9 3 4 34
2/2 2 0 0 43
2/3 1 0 0 53
3/3 0 0 1 76
VKORC1
37 82 7
45 12 30
18 6 63

TABLE 123-9 Comparison of the Pharmacologic Properties of the Direct Oral Anticoagulants CHARACTERISTIC Target Prodrug…

Harrison's 22e, p.953

CHARACTERISTIC RIVAROXABAN APIXABAN EDOXABAN DABIGATRAN
Target Factor Xa Factor Xa Factor Xa Thrombin
No No No
Bioavailability 80% 60% 50% 6%
qd (bid) bid qd
Half-life 7–11 h 12 h 9–11 h 12–17 h
33% (66%) 25% 35%
Interactions 3A4/P-gp 3A4/P-gp P-gp P-gp